📋 Case Study

Electrolyte Manufacturing for EV Batteries — BASF Ulsan Plant

HF generation during synthesis; 42% fluorine lost as CaF₂ sludge; high energy demand for cryogenic purification

🏗️ Project Overview

New LiPF₆ synthesis line with closed-loop fluorine management

🎯 Challenge

HF generation during synthesis; 42% fluorine lost as CaF₂ sludge; high energy demand for cryogenic purification

🔧 Design Approach

Adopted electrochemical fluorination with regenerative HF scrubbing; installed heat-integrated distillation with ceramic membranes

📐 Design Diagram

Electrolyte Manufacturing for EV Batteries — BASF Ulsan Plant HF Generation 42% F lost as CaF₂ sludge Cryogenic purification → high energy Electrochemical Fluorination + Regenerative HF Scrubbing Heat-Integrated Distillation Ceramic Membrane Separation Fluorine Recovery 98.7% Energy Consumption 4.1 kWh/kg (vs. 8.3) Process Integration LiPF₆

AI-generated project design illustration

📐 Key Calculations

Fluorine Recovery Rate

Recovered F / Input F × 100
Result: 98.7%
Reduces raw material cost and regulatory reporting burden

Specific Energy Consumption

kWh / kg LiPF₆
Result: 8.3 → 4.1
Key competitiveness lever in battery supply chain

📊 Results

HF emissions reduced by 99.4%; fluorine purchase costs down 31%; passed ISO 14067 carbon footprint verification

💡 Lessons Learned

  • Material compatibility (e.g., Ni–Mo alloys) is non-negotiable for HF service
  • Real-time fluorine mass balance monitoring prevents batch rejection

Key Takeaways

  • 1Material compatibility (e.g., Ni–Mo alloys) is non-negotiable for HF service
  • 2Real-time fluorine mass balance monitoring prevents batch rejection